Four compounds of phosphite ester and phosphoramide containing azido groups were synthesized. The molecular structure of the products has been confirmed by IR，1HNMR，FAB-MS and elemental analysis.

首次合成了叠氮亚磷酯及叠氮磷酰胺类化合物，并IR、1HNMR、FAB-MS及元素分析对化合物结构进行了鉴定。